To Dial French Guiana, you should start with dialing the GF international code +594 then the appropriate area code and the local number.

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How to dial French Guiana
Example phone dialings for French Guiana
NationalInternational
Fixed Line0594 10 12 34+594 594 10 12 34
Mobile0694 20 12 34+594 694 20 12 34
Fixed Line Or Mobile0594 10 12 34+594 594 10 12 34
Toll Free0800 01 23 45+594 800 01 23 45
Voip0976 01 23 45+594 976 01 23 45